The answer to riddle #4 is program ‘debug.exe’. You can use it to view slack space of files:

Thanks for trying & next riddle on Friday!
The Riddle:
Today’s riddle is very short. You are on a lonely island. You have a new laptop with a plain vanilla installation of Windows XP and a PIN-locked mobile phone with emergency calls disabled. The phone’s PIN is hidden in a slack space of c:\boot.ini. Using only OS tools retrieve the PIN, unlock the phone, call for help and leave the island.
Answer here